A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides.
نویسندگان
چکیده
A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 4 شماره
صفحات -
تاریخ انتشار 2013